Copper??Catalyzed Intermolecular Amination of Acidic Aryl C H Bonds with Primary Aromatic Amines

H Zhao, M Wang, W Su, M Hong

文献索引：Zhao, Huaiqing; Wang, Min; Su, Weiping; Hong, Maochun Advanced Synthesis and Catalysis, 2010 , vol. 352, # 8 p. 1301 - 1306

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被引用次数: 85

摘要

Abstract A copper-catalyzed intermolecular aerobic oxidative C [BOND] H bond amination of various polyfluorobenzenes with an array of primary aromatic amines was achieved for the first time. The reactivity of the polyfluorobenzenes was observed to depend on the acidity of C [BOND] H bonds. Under similar reaction conditions, the C [BOND] H bond amination of azoles also occurred.