Mass Spectrometry and Organic Analysis, part 14. The photolysis and mass spectra of medium and large ring ketones from C9 to C16

KH Schulte??Elte, B Willhalm, AF Thomas…

文献索引：Schulte-Elte,K.H. et al. Helvetica Chimica Acta, 1971 , vol. 54, p. 1759 - 1767

全文：HTML全文

被引用次数: 15

摘要

Abstract The photolysis of cyclic ketones from C 9 to C 16 has been carried out, and formation of cyclobutanols observed in only C 11 to C 16. Although in the mass spectrometer cyclobutanols are not formed, an initial transfer of a γ-hydrogen atom to the carbonyl group is shown to occur in the mass spectra of all cyclic ketones higher than C 10.