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Chemische Berichte

Carbanionisch induzierte [1, 3]??Wanderungen π??und koordinativ ungesättigter Gruppen

D Hellwinkel, F Lämmerzahl, G Hofmann

文献索引：Hellwinkel, Dieter; Laemmerzahl, Frank; Hofmann, Gunter Chemische Berichte, 1983 , vol. 116, # 10 p. 3375 - 3405

全文：HTML全文

被引用次数: 33

摘要

Abstract Gemäß einem allgemeinen Reaktionsschema reagieren o-Lithioarylester 4a, b,- amide 13a, b, 17b und-amidine 39b von nicht enolisierbaren Carbonsäuren ebenso wie ein entsprechendes Diphenylphosphinsäureamid 51b unter milden Bedingungen zu den intensiv gefärbten Lithiumderivaten von o-Acylphenolen 6a, b und o-Acylarenaminen 15a, b, 18a, 41a, 52a, die abschließend zu den Neutralprodukten 7a, b, 14a, b, 18b, 41b, 52b ...

Benzamide, N-p-tolyl-结构式

Benzamide, N-p-...

~%

N-(2-bromo-4-methylphenyl)-N-methylbenzamide结构式

N-(2-bromo-4-me...

N-(2-Bromo-4-methylphenyl)benzamide结构式

N-(2-Bromo-4-me...

硫酸二甲酯结构式

硫酸二甲酯

~62%

N-(2-bromo-4-methylphenyl)-N-methylbenzamide结构式

N-(2-bromo-4-me...

2-溴-4-甲基苯酚结构式

2-溴-4-甲基苯酚

苯甲酰氯结构式

~72%

benzoic acid,2-bromo-4-methylphenol结构式

benzoic acid,2-...

2-bromo-N-diphenylphosphoryl-N,4-dimethylaniline结构式

2-bromo-N-diphe...

~22%

2-diphenylphosphoryl-N,4-dimethylaniline结构式

2-diphenylphosp...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

2-diphenylphosphoryl-N,4-dimethylaniline结构式

2-diphenylphosp...

氯代二苯基膦结构式

氯代二苯基膦

~%

2-diphenylphosphoryl-N,4-dimethylaniline结构式

2-diphenylphosp...

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

2-diphenylphosphoryl-N,4-dimethylaniline结构式

2-diphenylphosp...

二苯基次膦酰氯结构式

二苯基次膦酰氯

~%

2-diphenylphosphoryl-N,4-dimethylaniline结构式

2-diphenylphosp...

4,4'-二甲基二苯胺结构式

4,4'-二甲基二苯胺

特戊酰氯结构式

~58%

2,2-dimethyl-N,N-bis(4-methylphenyl)propanamide结构式

2,2-dimethyl-N,...

(Z)-N,4-Dimethyl-2-((4-methylphenyl)(4-methylphenylimino)methyl)anilin结构式

(Z)-N,4-Dimethy...

~62%

对甲苯胺结构式

[5-methyl-2-(methylamino)phenyl]-(4-methylphenyl)methanone结构式

[5-methyl-2-(me...

2-溴-4-甲基苯酚结构式

2-溴-4-甲基苯酚

特戊酰氯结构式

~82%

(2-bromo-4-methylphenyl) 2,2-dimethylpropanoate结构式

(2-bromo-4-meth...

特戊酰氯结构式

~%

N-(2-bromo-4-methylphenyl)-2,2-dimethylpropanamide结构式

N-(2-bromo-4-me...

对甲苯胺结构式

~%

N-(2-bromo-4-methylphenyl)-2,2-dimethylpropanamide结构式

N-(2-bromo-4-me...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

2-bromo-N-(2,2-diphenylethenyl)-N,4-dimethylaniline结构式

2-bromo-N-(2,2-...

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

2-bromo-N-(2,2-diphenylethenyl)-N,4-dimethylaniline结构式

2-bromo-N-(2,2-...

二苯基乙醛结构式

二苯基乙醛

~%

N-(2,2-diphenylethenyl)-N,4-dimethylaniline结构式

N-(2,2-diphenyl...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

N-(2,2-diphenylethenyl)-N,4-dimethylaniline结构式

N-(2,2-diphenyl...

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

N-(2,2-diphenylethenyl)-N,4-dimethylaniline结构式

N-(2,2-diphenyl...

2-bromo-N-(2,2-diphenylethenyl)-N,4-dimethylaniline结构式

2-bromo-N-(2,2-...

~%

N-(2,2-diphenylethenyl)-N,4-dimethylaniline结构式

N-(2,2-diphenyl...

Benzamide, N-p-tolyl-结构式

Benzamide, N-p-...

~%

[5-methyl-2-(methylamino)phenyl]-phenylmethanone结构式

[5-methyl-2-(me...

N-(2-bromo-4-methylphenyl)-N-methylbenzamide结构式

N-(2-bromo-4-me...

~%

[5-methyl-2-(methylamino)phenyl]-phenylmethanone结构式

[5-methyl-2-(me...

N-(2-Bromo-4-methylphenyl)benzamide结构式

N-(2-Bromo-4-me...

~%

[5-methyl-2-(methylamino)phenyl]-phenylmethanone结构式

[5-methyl-2-(me...

2-溴-4-甲基苯酚结构式

2-溴-4-甲基苯酚

~%

(4-methylphenyl) 2,2-dimethylpropanoate结构式

(4-methylphenyl...

(2-bromo-4-methylphenyl) 2,2-dimethylpropanoate结构式

(2-bromo-4-meth...

~%

(4-methylphenyl) 2,2-dimethylpropanoate结构式

(4-methylphenyl...

2-溴-4-甲基苯酚结构式

2-溴-4-甲基苯酚

~%

1-(2-hydroxy-5-methylphenyl)-2,2-dimethylpropan-1-one结构式

1-(2-hydroxy-5-...

特戊酰氯结构式

~%

1-(2-hydroxy-5-methylphenyl)-2,2-dimethylpropan-1-one结构式

1-(2-hydroxy-5-...

(2-bromo-4-methylphenyl) 2,2-dimethylpropanoate结构式

(2-bromo-4-meth...

~%

对甲酚结构式

1-(2-hydroxy-5-methylphenyl)-2,2-dimethylpropan-1-one结构式

1-(2-hydroxy-5-...

9-氨基菲结构式

苯甲酰氯结构式

~41%

N-phenanthren-9-ylbenzamide结构式

N-phenanthren-9...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

硫酸二甲酯结构式

硫酸二甲酯

~89%

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

Propanamide,2,2-dimethyl-N-(4-methylphenyl)-结构式

Propanamide,2,2...

~%

N-(2-bromo-4-methylphenyl)-N,2,2-trimethylpropanamide结构式

N-(2-bromo-4-me...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

N-(2-bromo-4-methylphenyl)-N,2,2-trimethylpropanamide结构式

N-(2-bromo-4-me...

特戊酰氯结构式

~%

N-(2-bromo-4-methylphenyl)-N,2,2-trimethylpropanamide结构式

N-(2-bromo-4-me...

对甲苯胺结构式

~%

N-(2-bromo-4-methylphenyl)-N,2,2-trimethylpropanamide结构式

N-(2-bromo-4-me...

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

N-(2-bromo-4-methylphenyl)-N,2,2-trimethylpropanamide结构式

N-(2-bromo-4-me...

N-(2-bromo-4-methylphenyl)-2,2-dimethylpropanamide结构式

N-(2-bromo-4-me...

硫酸二甲酯结构式

硫酸二甲酯

~13%

N-(2-bromo-4-methylphenyl)-N,2,2-trimethylpropanamide结构式

N-(2-bromo-4-me...

特戊酰氯结构式

~%

2,2-dimethyl-1-[5-methyl-2-(methylamino)phenyl]propan-1-one结构式

2,2-dimethyl-1-...

Propanamide,2,2-dimethyl-N-(4-methylphenyl)-结构式

Propanamide,2,2...

~%

2,2-dimethyl-1-[5-methyl-2-(methylamino)phenyl]propan-1-one结构式

2,2-dimethyl-1-...

N-(2-bromo-4-methylphenyl)-N,2,2-trimethylpropanamide结构式

N-(2-bromo-4-me...

~%

2,2-dimethyl-1-[5-methyl-2-(methylamino)phenyl]propan-1-one结构式

2,2-dimethyl-1-...

N-(2-bromo-4-methylphenyl)-2,2-dimethylpropanamide结构式

N-(2-bromo-4-me...

~%

2,2-dimethyl-1-[5-methyl-2-(methylamino)phenyl]propan-1-one结构式

2,2-dimethyl-1-...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

2-溴-N,N,4-三甲基苯胺结构式

2-溴-N,N,4-三甲基苯胺

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

2-溴-N,N,4-三甲基苯胺结构式

2-溴-N,N,4-三甲基苯胺

N-(2-bromo-4-methylphenyl)-N-trimethylsilylbenzamide结构式

N-(2-bromo-4-me...

~27%

N-(2-Bromo-4-methylphenyl)benzamide结构式

N-(2-Bromo-4-me...

(2-氨基-5-甲基苯基)(苯基)甲酮结构式

(2-氨基-5-甲基苯基)(苯基)甲酮

N-(4-methyl-2-trimethylsilylphenyl)benzamide结构式

N-(4-methyl-2-t...

N-phenanthren-9-ylbenzamide结构式

N-phenanthren-9...

~86%

N-(10-bromophenanthren-9-yl)benzamide结构式

N-(10-bromophen...

9-氨基菲结构式

~%

N-(10-bromophenanthren-9-yl)benzamide结构式

N-(10-bromophen...

苯甲酰氯结构式

~%

N-(10-bromophenanthren-9-yl)benzamide结构式

N-(10-bromophen...

叔丁基锂结构式

N-(2-Brom-4-methylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzamid结构式

N-(2-Brom-4-met...

~18%

N-(2-bromo-4-methylphenyl)-4-methylbenzenesulfonamide结构式

N-(2-bromo-4-me...

对甲基苯甲酸结构式

对甲基苯甲酸

详细

N-(2-Brom-4-methylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzamid结构式

N-(2-Brom-4-met...

~%

N-(2-bromo-4-methylphenyl)-4-methylbenzenesulfonamide结构式

N-(2-bromo-4-me...

对甲基苯甲酸结构式

对甲基苯甲酸

4-methyl-N-[4-methyl-2-(4-methylbenzoyl)phenyl]benzenesulfonamide结构式

4-methyl-N-[4-m...

特戊酰氯结构式

N-甲基苯胺结构式

~60%

N,2,2-trimethyl-N-phenylpropanamide结构式

N,2,2-trimethyl...

叔丁基锂结构式

N-(2-Brom-4-methylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzamid结构式

N-(2-Brom-4-met...

~45%

N-(2-bromo-4-methylphenyl)-4-methylbenzenesulfonamide结构式

N-(2-bromo-4-me...

对甲基苯甲酸结构式

对甲基苯甲酸

详细

N-(2-Brom-4-methylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzamid结构式

N-(2-Brom-4-met...

~%

N-(2-bromo-4-methylphenyl)-4-methylbenzenesulfonamide结构式

N-(2-bromo-4-me...

对甲基苯甲酸结构式

对甲基苯甲酸

4-methyl-N-[4-methyl-2-(4-methylbenzoyl)phenyl]benzenesulfonamide结构式

4-methyl-N-[4-m...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

2-bromo-N,4-dimethyl-N-trimethylsilylaniline结构式

2-bromo-N,4-dim...

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

2-bromo-N,4-dimethyl-N-trimethylsilylaniline结构式

2-bromo-N,4-dim...

正丁基锂结构式

2-bromo-N,4-dimethyl-N-trimethylsilylaniline结构式

2-bromo-N,4-dim...

~16%

N-butyl-N,4-dimethyl-2-trimethylsilylaniline结构式

N-butyl-N,4-dim...

9-氨基菲结构式

~%

N-(10-bromophenanthren-9-yl)-N-methylbenzamide结构式

N-(10-bromophen...

N-phenanthren-9-ylbenzamide结构式

N-phenanthren-9...

~%

N-(10-bromophenanthren-9-yl)-N-methylbenzamide结构式

N-(10-bromophen...

苯甲酰氯结构式

~%

N-(10-bromophenanthren-9-yl)-N-methylbenzamide结构式

N-(10-bromophen...

N-(10-bromophenanthren-9-yl)benzamide结构式

N-(10-bromophen...

硫酸二甲酯结构式

硫酸二甲酯

~69%

N-(10-bromophenanthren-9-yl)-N-methylbenzamide结构式

N-(10-bromophen...

9-氨基菲结构式

~%

[10-(methylamino)phenanthren-9-yl]-phenylmethanone结构式

[10-(methylamin...

N-phenanthren-9-ylbenzamide结构式

N-phenanthren-9...

~%

[10-(methylamino)phenanthren-9-yl]-phenylmethanone结构式

[10-(methylamin...

N-(10-bromophenanthren-9-yl)-N-methylbenzamide结构式

N-(10-bromophen...

~%

[10-(methylamino)phenanthren-9-yl]-phenylmethanone结构式

[10-(methylamin...

N-(10-bromophenanthren-9-yl)benzamide结构式

N-(10-bromophen...

~%

[10-(methylamino)phenanthren-9-yl]-phenylmethanone结构式

[10-(methylamin...

三甲基氯硅烷结构式

三甲基氯硅烷

2-溴-N,N,4-三甲基苯胺结构式

2-溴-N,N,4-三甲基苯胺

~64%

N,N,4-trimethyl-2-trimethylsilylaniline结构式

N,N,4-trimethyl...

甲基锂结构式

2-bromo-N,4-dimethyl-N-trimethylsilylaniline结构式

2-bromo-N,4-dim...

~50%

N,N,4-trimethyl-2-trimethylsilylaniline结构式

N,N,4-trimethyl...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

N,N,4-trimethyl-2-trimethylsilylaniline结构式

N,N,4-trimethyl...

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

N,N,4-trimethyl-2-trimethylsilylaniline结构式

N,N,4-trimethyl...

三甲基氯硅烷结构式

三甲基氯硅烷

N-(2-Bromo-4-methylphenyl)benzamide结构式

N-(2-Bromo-4-me...

~84%

N-(2-bromo-4-methylphenyl)-N-trimethylsilylbenzamide结构式

N-(2-bromo-4-me...

Benzamide, N-p-tolyl-结构式

Benzamide, N-p-...

~%

N-(2-bromo-4-methylphenyl)-N-trimethylsilylbenzamide结构式

N-(2-bromo-4-me...

benzoic acid,2-bromo-4-methylphenol结构式

benzoic acid,2-...

~%

2-羟基-5-甲基二苯甲酮结构式

2-羟基-5-甲基二苯甲酮

苯甲酸结构式

N,N-bis(4-methylphenyl)benzamide结构式

N,N-bis(4-methy...

叔丁基锂结构式

~%

4,4'-二甲基二苯胺结构式

4,4'-二甲基二苯胺

4-tert-butyl-N,N-bis(4-methylphenyl)benzamide结构式

4-tert-butyl-N,...

详细

N-(2-bromo-4-methylphenyl)-N-trimethylsilylbenzamide结构式

N-(2-bromo-4-me...

~30%

N-(2-Bromo-4-methylphenyl)benzamide结构式

N-(2-Bromo-4-me...

(2-氨基-5-甲基苯基)(苯基)甲酮结构式

(2-氨基-5-甲基苯基)(苯基)甲酮

N-(4-methyl-2-trimethylsilylphenyl)benzamide结构式

N-(4-methyl-2-t...

特戊酰氯结构式

对甲苯胺结构式

~75%

Propanamide,2,2-dimethyl-N-(4-methylphenyl)-结构式

Propanamide,2,2...

4,4'-二甲基二苯胺结构式

4,4'-二甲基二苯胺

苯甲酰氯结构式

~80%

N,N-bis(4-methylphenyl)benzamide结构式

N,N-bis(4-methy...

N,N-bis(4-methylphenyl)benzamide结构式

N,N-bis(4-methy...

叔丁基锂结构式

~%

4,4'-二甲基二苯胺结构式

4,4'-二甲基二苯胺

4-tert-butyl-N,N-bis(4-methylphenyl)benzamide结构式

4-tert-butyl-N,...

详细

三甲基氯硅烷结构式

三甲基氯硅烷

N-(2-Bromo-4-methylphenyl)benzamide结构式

N-(2-Bromo-4-me...

~47%

N-(4-methyl-2-trimethylsilylphenyl)benzamide结构式

N-(4-methyl-2-t...

N-(2-bromo-4-methylphenyl)-N-trimethylsilylbenzamide结构式

N-(2-bromo-4-me...

~32%

N-(2-Bromo-4-methylphenyl)benzamide结构式

N-(2-Bromo-4-me...

(2-氨基-5-甲基苯基)(苯基)甲酮结构式

(2-氨基-5-甲基苯基)(苯基)甲酮

N-(4-methyl-2-trimethylsilylphenyl)benzamide结构式

N-(4-methyl-2-t...

Benzamide, N-p-tolyl-结构式

Benzamide, N-p-...

~%

N-(4-methyl-2-trimethylsilylphenyl)benzamide结构式

N-(4-methyl-2-t...

2'-溴-4'-甲基乙酰苯胺结构式

2'-溴-4'-甲基乙酰苯胺

~%

2-bromo-N-diphenylphosphoryl-N,4-dimethylaniline结构式

2-bromo-N-diphe...

氯代二苯基膦结构式

氯代二苯基膦

~%

2-bromo-N-diphenylphosphoryl-N,4-dimethylaniline结构式

2-bromo-N-diphe...

N-(2-bromo-4-methylphenyl)-N-methylacetamide结构式

N-(2-bromo-4-me...

~%

2-bromo-N-diphenylphosphoryl-N,4-dimethylaniline结构式

2-bromo-N-diphe...

对甲苯胺结构式

对甲基苯甲酰氯结构式

对甲基苯甲酰氯

~96%

4-methyl-N-(4-methylphenyl)benzamide结构式

4-methyl-N-(4-m...

特戊酰氯结构式

~%

1-anilino-3,3-dimethylbutan-2-one结构式

1-anilino-3,3-d...

N-甲基苯胺结构式

~%

1-anilino-3,3-dimethylbutan-2-one结构式

1-anilino-3,3-d...

N,2,2-trimethyl-N-phenylpropanamide结构式

N,2,2-trimethyl...

~%

1-anilino-3,3-dimethylbutan-2-one结构式

1-anilino-3,3-d...

N-(3,3-dimethyl-2-oxobutyl)-2,2-dimethyl-N-phenylpropanamide结构式

N-(3,3-dimethyl...

特戊酰氯结构式

~%

N-(3,3-dimethyl-2-oxobutyl)-2,2-dimethyl-N-phenylpropanamide结构式

N-(3,3-dimethyl...

N-甲基苯胺结构式

~%

N-(3,3-dimethyl-2-oxobutyl)-2,2-dimethyl-N-phenylpropanamide结构式

N-(3,3-dimethyl...

N,2,2-trimethyl-N-phenylpropanamide结构式

N,2,2-trimethyl...

~%

1-anilino-3,3-dimethylbutan-2-one结构式

1-anilino-3,3-d...

N-(3,3-dimethyl-2-oxobutyl)-2,2-dimethyl-N-phenylpropanamide结构式

N-(3,3-dimethyl...