Kinetics and mechanism of the aminolysis of 4-nitrophenyl dithioacetate

EA Castro, F Ibanez, JG Santos…

文献索引：Castro, Enrique A.; Ibanez, Fernando; Santos, Jose G.; Ureta, Carmen Journal of Organic Chemistry, 1992 , vol. 57, # 26 p. 7024 - 7028

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被引用次数: 29

摘要

The reaction of the title substrate with a series of secondary alicylic amines has been the subject of a kinetic study in aqueous solution, 25 OC, ionic strength 0.2 M (KCl). With the amine in excess, pseudo-first-order rate constants (kobsd) are observed. The order in amine varies from 1 to 2 depending on the basicity of the amine and the reaction conditions. A reaction scheme is deduced on the basis of the existence of zwitterionic (Ti) and anionic ( ...