Tetrahedron

Cryoelectrochemistry: electrochemical reduction of 2 (RS)-methyl 1-(tert-butoxycarbonyl)-2-iodomethyl-2, 5-dihydropyrrole-2-carboxylate

…, J Rodrigues, PG Turner, TJ Donohoe, RG Compton

文献索引：Banks, Craig E.; Evans, Russell G.; Rodrigues, Jason; Turner, Peter G.; Donohoe, Timothy J.; Compton, Richard G. Tetrahedron, 2005 , vol. 61, # 9 p. 2365 - 2372

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被引用次数: 7

摘要

Cryoelectrochemisty utilising cyclic voltammetry and chronoamperometry has been applied giving an insight into an organic mechanism at low temperature allowing the number of electrons participating in the reaction to be deduced from potential step experiments without recourse to bulk chrono-coulometery while the low temperature allow otherwise voltammetry invisible molecules such as iodopentane to be studied. ... With a continued interest in the stereoselective ...