Tetrahedron letters

Effect of sodium naphthalenide, a key SET reagent, on trifluoroacetyl derivatives

A Banerji, D Bandyopadhyay, B Basak, KR Sur…

文献索引：Banerji, Avijit; Bandyopadhyay, Debasish; Basak, Bidyut; Sur, Kumar R.; Paul, Jyoti N.; Banerji, Julie; Chatterjee, Asima Tetrahedron Letters, 2005 , vol. 46, # 41 p. 7033 - 7035

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被引用次数: 3

摘要

Aromatic trifluoroacetyl derivatives on treatment with single electron transfer (SET) reagent, sodium naphthalenide, yield symmetrical defluorinated dimers, whereas for aliphatic trifluoroacetyl compounds the reaction usually fails. Investigations have been made for different substituents as well as for similar types of chloro and bromo compounds to establish the scope of the reaction.