Journal of Organometallic Chemistry

Application of dimeric cyclopalladated complex of tribenzylamine as an efficient catalyst in the Heck cross-coupling reaction

AR Hajipour, F Rafiee

文献索引：Hajipour, Abdol R.; Rafiee, Fatemeh Journal of Organometallic Chemistry, 2011 , vol. 696, # 13 p. 2669 - 2675

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被引用次数: 28

摘要

Abstract The activity of [Pd {C 6 H 4 (CH 2 N (CH 2 Ph) 2)}(μ-Br)] 2 complex was investigated in the Heck–Mizoroki C–C cross-coupling reaction. This complex is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides and also arenesulfonyl chlorides. The cross-coupled products were produced in excellent yields in short reaction time using a catalytic amount of [Pd {C 6 H 4 (CH 2 N (CH 2 Ph) 2)(μ-Br)] 2 ...