Pyridine nucleotide chemistry. A new mechanism for the hydroxide-catalyzed hydrolysis of the nicotinamide-glycosyl bond

RW Johnson, TM Marschner…

文献索引：Journal of the American Chemical Society, , vol. 110, # 7 p. 2257 - 2263

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被引用次数: 43

摘要

... 0002-7863/88/1510-2257$01.50/0 0 1988 American Chemical Society ... is the chemical shift of the carbon atom in the un- ionized diol, bA is the chemical shift of ... for the slower associative formation of ZHPC allows this latter reaction to eventually dominate the chemistry above pH ...