Synthesis and structure of a new scorpionate-dithio carboxyl oxovanadium complex and an organic dithio carboxyl compound

FY Bai, XT Li, GS Zhu, YH Xing

文献索引：Bai; Li; Zhu; Xing Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2010 , vol. 75, # 5 p. 1388 - 1393

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摘要

A new complex of oxovanadium (IV), V2O2 [(HB (pz) 3) 2 (pyrro) 2 (1) and a dimer-dithio carboxyl compound (C5H8NS2) 2 (2) have been synthesized by the reaction of VOSO4· nH2O with NaHB (pz) 3 and pyrrolidine dithio carboxylic acid ammonium salt. They were characterized by element analysis, IR spectra, UV–vis spectra and X-ray diffraction. Structural analyses of 1 and 2 gave the following parameters: 1, triclinic, P-1, a= 7.732 (4) ...