Sodium Borohydride??Nickel Chloride??Methanol Catalytic System for Regioselective Reduction of Electron??Rich Conjugated Dienes and Reductive Cleavage of Allyl …

…, ZR Zhang, L Huang, LW Xu, HF Jiang

文献索引：Yin, Biao-Lin; Cai, Cong-Bi; Lai, Jin-Qiang; Zhang, Ze-Ren; Huang, Li; Xu, Li-Wen; Jiang, Huan-Feng Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3319 - 3324

全文：HTML全文

被引用次数: 2

摘要

Abstract The regioslective reduction of electron-rich dienes to monoolefins and the reductive cleavage of allyl esters were fulfilled by employing a sodium borohydride-nickel chloride- methanol catalytic system with exceedingly simple manipulations and high functional group tolerability. Both of the reductive reactions may involve π-allylnickel intermediates generated from fresh nickel boride.