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The Action of Bases on Organic Halogen Compounds. IV. The Action of the Lithium Salts of Aliphatic Amines on some Organic Halogen Compounds

CH Horning, FW Bergstrom

文献索引:Horning; Bergstrom Journal of the American Chemical Society, 1945 , vol. 67, p. 2110

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被引用次数: 7

摘要

Aromatic amines are formed in fair yield by the action of a solution of an alkali amide upon an aryl halide in liquid amm~ nia,~.~ but this reaction is sometimes accompanied by a rearrangement to the ortho position. 8 In the present article is reported the results of a preliminary investigation of the action of lithium dialkylamides (the lithium alcoholates of the ammonia system) on a number of aliphatic and aromatic halides dissolved in diethyl ether.