Journal of Organometallic Chemistry

Reaction of (bromodifluoromethyl) phenyldimethylsilane with organometallic reagents

T Fuchikami, I Ojima

文献索引：Fuchikami, Takamasa; Ojima, Iwao Journal of Organometallic Chemistry, 1981 , vol. 212, # 2 p. 145 - 153

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被引用次数: 20

摘要

Abstract A new fluorine-containing organosilicon compound,(bromodifluoromethyl)- phenyldimethylsilane (II), was synthesized by the N-bromosuccinimide (NBS) bromination of difluoromethyl) phenyldimethylsilane (I), which was prepared from phenyldimethylsilyllithium and chlorodifluoromethane. Compound II reacted with dimethyl sulfoxide to give dimethyl sulfide and phenyldimethylfluorosilane in quantitative yield. The reaction of II with ...