Synthesis of t-Butylsilicon Compounds by the Wurtz-Fitting Reaction1

CC Chappelow Jr, RL Elliott…

文献索引：Chappelow,C.C. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 1409 - 1414

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被引用次数: 6

摘要

The proximity of the boiling points of the silane starting material and the t-butylated product made separations difficult, so yields were obtained by vapor phase chromatography of the reaction mixtures. The presence of a copper amalgam did not show any catalytic effect'upon the yield of t-butylated product. In the t-butylation of tetraethoxysilane, a slightly lower yield was obtained by the use of a sodium dispersion than the yields obtained by using sodium ...