Carbon-oxygen bond cleavage of esters promoted by hydrido-and alkylcobalt (I) complexes having triphenylphosphine ligands. Isolation of an insertion intermediate …
Y Hayashi, T Yamamoto, A Yamamoto…
文献索引：Hayashi, Yoshinori; Yamamoto, Takakazu; Yamamoto, Akio; Komiya, Sanshiro; Kushi, Yoshihiko Journal of the American Chemical Society, 1986 , vol. 108, # 3 p. 385 - 391
Abstract: Carbon-oxygen bonds in aryl and alkyl carboxylates (R'COOR) are selectively cleaved by CoH (N,)(PPh,),, and carboxylic esters R'COOCH, R'are formed by a Tischchenko type dimerization of aldehyde R'CHO, whereas the reaction of COM~(PP~~)~ with the esters yields ketones R'COMe. The reaction products are accounted for by assuming insertion of the ester C= O double bond into the Co-H or Co-Me bond, followed ...
