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Chemically modified dansyl probes: a fluorescent diagnostic for ion and proton detection in solution and in polymers

NA O'Connor, ST Sakata, H Zhu, KJ Shea

文献索引:O'Connor, Naphtali A.; Sakata, Steven T.; Zhu, Huide; Shea, Kenneth J. Organic Letters, 2006 , vol. 8, # 8 p. 1581 - 1584

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被引用次数: 23

摘要

The fluorescence emission intensity of the dansyl group is significantly diminished upon appending an ethyldimethylamino group to the N1 nitrogen substituent. Addition of acids and metal ions (ie, Zn2+) to solutions of trimethylethylenediamine naphthalene sulfonamide (trinsyl) 2 produces a> 25-fold increase in fluorescence intensity. Trinsyl probe 2 has been used as a diagnostic for the diffusion of protons and metal ions in a network polymer as ...