Selective on-line deuteration in gas chromatography-mass spectrometry for the investigation of dissociative ionization of silicon-containing compounds

…, VG Zaikin, NV Ushakov, VM Vdovin

文献索引：Mikaya, A. I.; Zaikin, V. G.; Ushakov, N. V.; Vdovin, V. M. Journal of Organometallic Chemistry, 1985 , vol. 284, p. 5 - 12

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被引用次数: 6

摘要

Abstract A method for specific gas-phase deuteration of unsaturated silicon-containing compounds over pre-heterogenized Wilkinson's catalyst (a solution of (Ph 3 P) 3 RhCl in Carbowax 20M coated on Chromaton) in the reaction column connected to the mass spectrometer is described. This method was employed to study the dissociative ionization of the corresponding saturated analogues. With the aid of the mass spectra of the dideutero ...