N-Heterocyclic Carbene C, S Palladium (II) π-Allyl Complexes: Synthesis, Characterization, and Catalytic Application In Allylic Amination Reactions

D Krishnan, M Wu, M Chiang, Y Li, PH Leung…

文献索引：Krishnan, Deepa; Wu, Meiyi; Chiang, Minyi; Li, Yongxin; Leung, Pak-Hing; Pullarkat, Sumod A. Organometallics, 2013 , vol. 32, # 8 p. 2389 - 2397

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被引用次数: 17

摘要

A series of five-membered N-heterocyclic carbene C, S palladium (II) π-allyl complexes were successfully developed and characterized. Structural analyses of these complexes revealed that the organopalladium chelates adopt a skew-envelope conformation with a trans disposition of the substituents on the metal chelate rings. Utilizing these C, S palladium (II) π- allyl complexes as catalysts, a catalytic system for the allylic amination reaction has been ...