4 7 6 chemical shifi of the substituent at C-4 when it is at the shielding zone of the unsaturated chain attached to (2-3. For example, the signal of 4-H appeared at 6 3.58 ppm for 12a and at 6 4.19 ppm for 13a; concomitantly, the signal of the COzMe appeared at 6 3.81 ppm for 1 2 s and at 6 3.64 ppm for 13a.