Synthesis of fused polycycles by 1, 4-palladium migration chemistry

Q Huang, MA Campo, T Yao, Q Tian…

文献索引：Huang, Qinhua; Campo, Marino A.; Yao, Tuanli; Tian, Qingping; Larock, Richard C. Journal of Organic Chemistry, 2004 , vol. 69, # 24 p. 8251 - 8257

全文：HTML全文

被引用次数: 76

摘要

Novel palladium migration/arylation methodology for the synthesis of complex fused polycycles has been developed, in which one or more sequential Pd-catalyzed intramolecular migration processes involving CH activation are employed. The chemistry works best with electron-rich aromatics, which is in agreement with the idea that these palladium-catalyzed CH activation reactions parallel electrophilic aromatic substitution.