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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Synthesis

Synthesis of quinolines and 2H-dihydropyrroles by nucleophilic substitution at the nitrogen atom of oxime derivatives

M Kitamura, M Yoshida, T Kikuchi, K Narasaka

文献索引：Kitamura, Mitsuru; Yoshida, Masayuki; Kikuchi, Takashi; Narasaka, Koichi Synthesis, 2003 , # 15 p. 2415 - 2426

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被引用次数: 20

摘要

Abstract Isomerization of oxime derivatives was researched in detail to find out the methods for the syn-anti isomerization of O-substituted oximes. Based on these findings were developed simple methods for the preparation of aza-heterocycles from both stereoisomers of oximes. Quinolines were synthesized from β-aryl ketone oximes by treatment with trifluoroacetic anhydride and 4-chloranil. γ, δ-Unsaturated O-methoxyacetyloximes were ...

3-苯丙酰氯结构式

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1-phenyloct-6-en-3-one结构式

1-phenyloct-6-e...

3-苯丙酸结构式

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1-phenyloct-6-en-3-one结构式

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trans-5-bromo-2-pentene结构式

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N-甲氧基-N-甲基-3-苯基-丙酰胺结构式

N-甲氧基-N-甲基-3-苯基-丙酰胺

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1-phenyloct-6-en-3-one结构式

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3-苯丙酰氯结构式

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6-methyl-1-phenylhept-6-en-3-one结构式

6-methyl-1-phen...

3-苯丙酸结构式

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6-methyl-1-phenylhept-6-en-3-one结构式

6-methyl-1-phen...

4-溴-2-甲基丁-1-烯结构式

4-溴-2-甲基丁-1-烯

N-甲氧基-N-甲基-3-苯基-丙酰胺结构式

N-甲氧基-N-甲基-3-苯基-丙酰胺

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6-methyl-1-phenylhept-6-en-3-one结构式

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(E)-4-(3-methoxyphenyl)butan-2-one oxime结构式

(E)-4-(3-methox...

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(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

未登录结构式

~94%

(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

4-(4-甲氧基苯基)-3-丁烯-2-酮结构式

4-(4-甲氧基苯基)-3-丁烯-2-酮

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(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

(3-CYANOBUTYL)TRICHLOROSILANE结构式

(3-CYANOBUTYL)T...

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(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

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(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

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3-甲氧基苯甲醛结构式

3-甲氧基苯甲醛

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(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

茴香基丙酮结构式

茴香基丙酮

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(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

1-(3-methoxyphenyl)-butane-3-one结构式

1-(3-methoxyphe...

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(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

未登录结构式

~88%

6-甲氧基-2-甲基喹啉结构式

6-甲氧基-2-甲基喹啉

2-methyl-1-azaspiro[4.5]deca-1,6,9-trien-8-one结构式

2-methyl-1-azas...

(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

~%

6-甲氧基-2-甲基喹啉结构式

6-甲氧基-2-甲基喹啉

6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

4-(4-甲氧基苯基)-3-丁烯-2-酮结构式

4-(4-甲氧基苯基)-3-丁烯-2-酮

~%

6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

(3-CYANOBUTYL)TRICHLOROSILANE结构式

(3-CYANOBUTYL)T...

~%

6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

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6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

3-甲氧基苯甲醛结构式

3-甲氧基苯甲醛

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6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

~%

6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

(9CI)-3,4-二氢-6-甲氧基-2-甲基喹啉结构式

(9CI)-3,4-二氢-6-...

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6-甲氧基-2-甲基喹啉结构式

6-甲氧基-2-甲基喹啉

6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

茴香基丙酮结构式

茴香基丙酮

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6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

1-(3-methoxyphenyl)-butane-3-one结构式

1-(3-methoxyphe...

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6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

(E)-4-(3-methoxyphenyl)butan-2-one oxime结构式

(E)-4-(3-methox...

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6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

未登录结构式

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6-Methoxy-2-methyl-1,2,3,4-tetrahydroquinoline结构式

6-Methoxy-2-met...

未登录结构式

~0%

6-甲氧基-2-甲基喹啉结构式

6-甲氧基-2-甲基喹啉

2-methyl-1-azaspiro[4.5]deca-1,6,9-trien-8-one结构式

2-methyl-1-azas...

4-(4-甲氧基苯基)-3-丁烯-2-酮结构式

4-(4-甲氧基苯基)-3-丁烯-2-酮

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2-methyl-1-azaspiro[4.5]deca-1,6,9-trien-8-one结构式

2-methyl-1-azas...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

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2-methyl-1-azaspiro[4.5]deca-1,6,9-trien-8-one结构式

2-methyl-1-azas...

茴香基丙酮结构式

茴香基丙酮

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2-methyl-1-azaspiro[4.5]deca-1,6,9-trien-8-one结构式

2-methyl-1-azas...

甲基异丙基甲酮结构式

甲基异丙基甲酮

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N-[1-(4-methoxyphenyl)-4-methylpentan-3-ylidene]hydroxylamine结构式

N-[1-(4-methoxy...

alpha,alpha-dimethyl anisyl acetone结构式

alpha,alpha-dim...

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N-[1-(4-methoxyphenyl)-4-methylpentan-3-ylidene]hydroxylamine结构式

N-[1-(4-methoxy...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

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N-[1-(4-methoxyphenyl)-4-methylpentan-3-ylidene]hydroxylamine结构式

N-[1-(4-methoxy...

1-(4-methoxyphenyl)-4-methylpentan-3-one结构式

1-(4-methoxyphe...

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N-[1-(4-methoxyphenyl)-4-methylpentan-3-ylidene]hydroxylamine结构式

N-[1-(4-methoxy...

3-溴-4-甲氧基苯甲醛结构式

3-溴-4-甲氧基苯甲醛

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4-(3-溴-4-甲氧基苯基)丁-2-酮结构式

4-(3-溴-4-甲氧基苯基)丁-2-酮

4-(对甲苯基)丁-3-烯-2-酮结构式

4-(对甲苯基)丁-3-烯-2-酮

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N-[4-(4-methylphenyl)butan-2-ylidene]hydroxylamine结构式

N-[4-(4-methylp...

对甲基苯甲醛结构式

对甲基苯甲醛

~%

N-[4-(4-methylphenyl)butan-2-ylidene]hydroxylamine结构式

N-[4-(4-methylp...

4-(4-甲基苯基)-2-丁酮结构式

4-(4-甲基苯基)-2-丁酮

~%

N-[4-(4-methylphenyl)butan-2-ylidene]hydroxylamine结构式

N-[4-(4-methylp...

trans-6-phenylhex-5-en-2-one结构式

trans-6-phenylh...

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N-(6-phenylhex-5-en-2-ylidene)hydroxylamine结构式

N-(6-phenylhex-...

4-溴-1-丁烯结构式

N-甲氧基-N-甲基-3-苯基-丙酰胺结构式

N-甲氧基-N-甲基-3-苯基-丙酰胺

~78%

1-phenylhept-6-en-3-one结构式

1-phenylhept-6-...

3-苯丙酰氯结构式

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1-phenylhept-6-en-3-one结构式

1-phenylhept-6-...

3-苯丙酸结构式

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1-phenylhept-6-en-3-one结构式

1-phenylhept-6-...

N-[1-(4-methoxyphenyl)-4-methylpentan-3-ylidene]hydroxylamine结构式

N-[1-(4-methoxy...

~77%

6-methoxy-2-propan-2-ylquinoline结构式

6-methoxy-2-pro...

甲基异丙基甲酮结构式

甲基异丙基甲酮

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6-methoxy-2-propan-2-ylquinoline结构式

6-methoxy-2-pro...

alpha,alpha-dimethyl anisyl acetone结构式

alpha,alpha-dim...

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6-methoxy-2-propan-2-ylquinoline结构式

6-methoxy-2-pro...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

6-methoxy-2-propan-2-ylquinoline结构式

6-methoxy-2-pro...

1-(4-methoxyphenyl)-4-methylpentan-3-one结构式

1-(4-methoxyphe...

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6-methoxy-2-propan-2-ylquinoline结构式

6-methoxy-2-pro...

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