Production and reactions of triplet CS: matrix infrared and ultraviolet spectra of C2S2

RB Bohn, Y Hannachi, L Andrews

文献索引：Bohn, Robert B.; Hannachi, Yacine; Andrews, Lester Journal of the American Chemical Society, 1992 , vol. 114, # 16 p. 6452 - 6459

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被引用次数: 41

摘要

Abstract: Matrix infrared and visible-ultraviolet absorption spectroscopy and ab initio electronic structure calculations have been used to characterize the reaction products from a Tesla coil Ar/CS2 discharge. The discharge is an excellent source of CS, which reacts with other molecules to form the major C3S2 product and the transient C2S2 species. The spectra of discharged mixed isotopic samples Ar/12CS2/'3CS2 and Ar/C32S2/C34S2 ...