Journal of Fluorine Chemistry

Reactions of perfluoroaromatic compounds with ethereal solutions of methylmagnesium iodide in the presence of silver (I) and copper (I) salts

AA Bogachev, LS Kobrina, GG Yakobson

文献索引：Bogachev, A. A.; Kobrina, L. S.; Yakobson, G. G. Journal of Fluorine Chemistry, 1990 , vol. 48, # 1 p. 85 - 97

全文：HTML全文

被引用次数: 3

摘要

Abstract The reactions of hexafluorobenzene, octafluorotoluene, decafluorodiphenyl, and octafluoronaphthalene with ethereal solutions of methylmagnesium iodide in the presence of AgCl or CuI gave the products of the methylation and 1-ethoxy-ethylation of the perfluorinated substrates, whose formation has been suggested to occur with participation of free radicals. Substitution of fluorine atoms by the 1-ethoxyethyl radicals in C6F5CF3 and ...