Tetrahedron letters

Stereocontrolled synthesis of tropanol derivatives via palladium-catalyzed reactions

JE Bäckvall, ZD Renko, SE Byström

文献索引：Baeckvall, J. E.; Renko, Z. D.; Bystroem, S. E. Tetrahedron Letters, 1987 , vol. 28, # 36 p. 4199 - 4202

全文：HTML全文

被引用次数: 32

摘要

A general method for the transformation of 1,3-cycloheptadienes to tropane alkaloid derivatives was developed. The procedure was applied to the stereocontrolled synthesis of the exo- and endo-tropanol derivatives and . The approach is based on a dual stereocontrol in the 1,4-functionalization of conjugated dienes. ... 6-Benzyloxy-1,3-cycloheptadiene was transformed to pseudotropine and tropine derivatives in a stereocontrolled manner. ... J. Org. Chem., 49 (1984), p. 3027 ...