Tetrahedron letters

Reactions of (1-chlorovinyl) diphenylphosphine oxide with organometallic reagents

C Cardellicchio, V Fiandanese, F Naso…

文献索引：Cardellicchio, Cosimo; Fiandanese, Vito; Naso, Francesco; Pietrusiewicz, K. Michal; Wisniewski, Witold Tetrahedron Letters, 1993 , vol. 34, # 19 p. 3135 - 3138

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被引用次数: 9

摘要

Abstract Direct substitutionof 1-chlorovinyl group by an aryl or an alkyl group in the reactions of (1-chlorovinyl) diphenylphosphine oxide with aryl and alkyl Grignard reagents was observed, whereas in its reactions with the corresponding cuprates addition across the double bond constituted the dominant reaction pathway.