Facile synthesis of cyanogen glycosides (R)-prunasin, linamarin and (S)-heterodendrin

N Nakajima, M Ubukata

文献索引：Nakajima, Noriyuki; Ubukata, Makoto Bioscience, Biotechnology and Biochemistry, 1998 , vol. 62, # 3 p. 453 - 458

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被引用次数: 7

摘要

A facile synthetic route is described to cyanogenic glycosides (R)-prunasin, linamarin and (S)-heterodendrin from O-(2, 3, 4, 6-tetra-O-acetyl-α-d-glucopyranosyl) trichloroace-timidate and the corresponding α-hydroxyamides by a 3-step reaction of glycosylation, cyanohydrin formation by dehydration of carboxamides, and deprotection.