The design and synthesis of novel IBiox N-heterocyclic carbene ligands derived from substituted amino-indanols

JN Levy, CM Latham, L Roisin, N Kandziora…

文献索引：Levy, Jean-Noel; Latham, Christopher M.; Roisin, Loic; Kandziora, Nadine; Fruscia, Paolo Di; White, Andrew J. P.; Woodward, Simon; Fuchter, Matthew J. Organic and Biomolecular Chemistry, 2012 , vol. 10, # 3 p. 512 - 515

全文：HTML全文

被引用次数: 13

摘要

A synthetic route towards a number of novel IBiox N-heterocyclic carbene (NHC) ligands has been developed. The resulting ligands have restricted flexibility and high steric demand. Preliminary studies have shown these ligands to give high levels of asymmetric induction in the copper-free allylic alkylation of cinnamyl bromide.