Reactions of diethyl dibromomalonate and ethyl 2, 2-dichloroacetoacetate with water and carbonyl compounds (aldehydes and ketones) in the presence of …
AB Terent'ev, TT Vasil'eva, NE Mysova…
文献索引：Terent'ev; Vasil'eva; Mysova; Chakhovskaya Russian Journal of Organic Chemistry, 2004 , vol. 40, # 7 p. 924 - 927
Abstract Diethyl dibromomalonate and ethyl 2, 2-dichloroacetoacetate are effectively reduced with the system pentacarbonyliron-proton-donor compound (water or butyl methyl ketone) to give the corresponding hydrodehalogenation products. These results provide a support for the previous assumption that the key reaction stage is reduction with pentacarbonyliron of initially formed radical to anion which is then involved in proton ...
