In this report, substituted coumarins are formed via Pechmann condensation using various substituted phenols and ethyl acetoacetates in the presence of xanthan sulfuric acid as a solid acid catalyst under solvent-free conditions. This method is very simple, cost-effective, and has shorter reaction times, and the catalyst could be reused. ... In this report, substituted coumarins are formed via Pechmann condensation using various substituted phenols and ethyl acetoacetates in ...