Organic letters

Preparation of Alcohols from Alkenes via the Homologation of Boronates with (Trimethylsilyl) diazomethane

JP Goddard, T Le Gall, C Mioskowski

文献索引：Goddard, Jean-Philippe; Le Gall, Thierry; Mioskowski, Charles Organic Letters, 2000 , vol. 2, # 10 p. 1455 - 1456

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被引用次数: 16

摘要

Simple procedures allowing for elongation of the carbon chain of organic molecules are often needed in the course of multistep syntheses. Several methods for the conversion of alkenes to the corresponding alkylmethanols have been described, such as the reaction of boron compounds with carbon monoxide in the presence of a hydride, followed by basic hydrolysis. 1 Other methods involve the reaction of a boron compound with a nucleophilic reagent possessing a ...