Preparatively useful dehydrogenative method for dodecahedrane synthesis

LA Paquette, Y Miyahara…

文献索引：Paquette, Leo A.; Miyahara, Yuji; Doecke, Christopher W. Journal of the American Chemical Society, 1986 , vol. 108, # 7 p. 1716 - 1718

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被引用次数: 14

摘要

MNDO, corrected by a multiplicative factor of 0.885, obtained by fitting the CH2 as stretch in propane. bSubject to a large experimental uncertainty.< From the dichroic ratios of about 20 IR bands. Some of the small difference between K, b) and KJy) and between K,(z) and K,(z) is probably due to slightly mixed polarization of the absorption at 496.5 and 488 nm. This has no effect on the proposed assignments and