Carbon-carbon bond formation by induced elimination from unsymmetrically substituted (allyl)(allyl') palladium complexes

A Goliaszewski, J Schwartz

文献索引：Goliaszewski, Alan; Schwartz, Jeffrey Journal of the American Chemical Society, 1984 , vol. 106, # 17 p. 5028 - 5030

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被引用次数: 66

摘要

" Unidentified C. material.* Oxidant added to MeCN solution of bis (ally1) at-30 OC. CIonic medium 0.1 M Bu4NBF, in MeCN; reference electrode Ag, AgCi; Pt working electrode;-30 OC. taneous reductive elimination from these complexes does not occur; alkyl groupsubstituted allylic complexes decompose by processes involving hydride transfer^.^ Reductive elimination of 1, 4-dienes from (73-allyl)(7$ alkenyl) palladium (II) species can ...