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Polymer-immobilized complexes of platinum (II): their precursors and preparation studied by high-resolution solid-state phosphorus-31 NMR using magic-angle …

CA Fyfe, JA Davies, HC Clark, PJ Hayes…

文献索引:Fyfe; Clark; Davies; Hayes; Wasylishen Journal of the American Chemical Society, 1983 , vol. 105, # 22 p. 6577 - 6584

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被引用次数: 28

摘要

Abstract: Solid-state, IP NMR employing high-power proton decoupling, cross-polarization, and magic-angle spinning has been used to characterize various polymer-immobilized phosphine ligands and their platinum complexes. The reduction of polymer (polystyrene cross-linked with divinylbenzene) bound phosphine oxide, to tertiary phosphine, was monitored by these solid-state 31P NMR techniques. The immobilization of a platinum ...