Oxidatively stable, aqueous europium (II) complexes through steric and electronic manipulation of cryptand coordination chemistry

NDH Gamage, Y Mei, J Garcia…

文献索引：Gamage, Nipuni-Dhanesha H.; Mei, Yujiang; Garcia, Joel; Allen, Matthew J. Angewandte Chemie - International Edition, 2010 , vol. 49, # 47 p. 8923 - 8925

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被引用次数: 30

摘要

The magnetic and optical properties of the divalent state of europium make this ion extremely attractive for use in materials,[1] catalysis,[2] luminescence,[3] magnetic,[4] and diagnostic-medical [5] applications. A major hindrance to the use of EuII in many of these applications is the extreme propensity of the ion to oxidize to EuIII, especially in aqueous solution. Research efforts aimed at increasing the stability of aqueous EuII have yielded ...