Mechanism of preferential enrichment, an unusual enantiomeric resolution phenomenon caused by polymorphic transition during crystallization of mixed crystals …
…, H Takahashi, T Ushio, T Nakai, K Hirotsu
文献索引：Tamura, Rui; Fujimoto, Daisuke; Lepp, Zsolt; Misaki, Kentaro; Miura, Hideyuki; Takahashi, Hiroki; Ushio, Takanori; Nakai, Tadashi; Hirotsu, Ken Journal of the American Chemical Society, 2002 , vol. 124, # 44 p. 13139 - 13153
The mechanism of Preferential Enrichment, an unusual enantiomeric resolution phenomenon observed upon recrystallization of a series of racemic crystals which are classified as a racemic mixed crystal with fairly ordered arrangement of the two enantiomers, has been studied. On the basis of the existence of polymorphs and the occurrence of the resulting polymorphic transition during crystallization from solution, the mechanism has ...
