Iridium??Catalyzed Enantioselective Hydrogenation of Cyclic Imines

M Chang, W Li, G Hou, X Zhang

文献索引：Chang, Mingxin; Li, Wei; Hou, Guohua; Zhang, Xumu Advanced Synthesis and Catalysis, 2010 , vol. 352, # 18 p. 3121 - 3125

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被引用次数: 23

摘要

Abstract A catalytic complex made from [Ir (COD) Cl] 2 [di-μ-chloro-bis (1, 5-cyclooctadiene) diiridium (I)] precursor and (S, S)-f-Binaphane ((R, R)-1, 1′-bis {(R)-4, 5-dihydro-3H- dinaphtho [1, 2-c: 2′, 1′-e] phosphepino} ferrocene) ligand effectively catalyzed the enantioselective hydrogenation of cyclic imines with high reactivity and good enantioselectivity.