Mechanism of the thermal decomposition of substituted tetraoxanes in benzene solution: effect of substituents on the activation parameters of the unimolecular …

…, EL Svartman, AI Cañizo, EJ Borkowski

文献索引：Cafferata; Eyler; Svartman; Canizo; Bor kowski Journal of Organic Chemistry, 1990 , vol. 55, # 3 p. 1058 - 1061

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被引用次数: 41

摘要

The kinetics and mechanism of the thermal decomposition reactions of three substituted tetraoxanes (benzophenone diperoxide, cyclohexanone diperoxide, and pinacolone diperoxide in benzene solution were investigated in the temperature range 108-165" C. The activation parameters for unimolecular reactions of molecules of this type are interpreted in terms of substituent effects in the tetraoxacyclohexane ring. Isokinetic relationships are ...