New bromo-substituted bicyclic oxalactam, 4 (e)-bromo-8-oxa-6-azabicyclo [3.2. 1] octan-7- one (1) was synthesized from sodium 3, 4-dihydro-2H-pyran-2-carboxylate. Sodium salt of 1 was found to be oligomerized with the simultaneous desalting in dimethylformamide at 25 ...