Journal of Organometallic Chemistry

Synthesis of pyridine N-imine complexes of methylcobaloxime and reactions of bis (dimethylglyoximato) methyl (Pyridine N-imine) cobalt with acid anyhydrides and …

Y Tsurita, T Saito, Y Sasaki

文献索引：Tsurita, Yasushi; Saito, Taro; Sasaki, Yukiyoshi Journal of Organometallic Chemistry, 1980 , vol. 202, # 1 p. 91 - 98

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被引用次数: 1

摘要

Abstract Pyridine N-imine complexes of methylcobaloxime, CH 3 Co (Hdmg) 2 (R 1—C 5 H n N+ N− H)(n= 4; R 1= H, 2-CH 3, 3-CH 3, 4-CH 3: n= 3; R 1= 2, 6-CH 3), have been synthesized by the reaction of CH 3 Co (Hdmg) 2 S (CH 3) 2 with a pyridine N-imine which is generated from a pyridine, hydroxylamine-O-sulfonic acid and K 2 CO 3. The reactions of CH 3 Co (Hdmg) 2 (C 5 H 5 N+ N− H) with acid anhydrides form new methylcobaloxime ...