Synthesis of α-Substituted Enoximes with Nucleophiles via Nitrosoallenes

…, T Morimoto, Y Nishiyama, K Kakiuchi

文献索引：Zhang, Huan; Tanimoto, Hiroki; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi Organic Letters, 2013 , vol. 15, # 20 p. 5222 - 5225

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被引用次数: 2

摘要

This paper reports nitrosoallene-mediated synthesis of α-substituted enoximes. Nucleophilic substitution of nitrosoallenes, a novel chemical species prepared from allenyl N- hydroxysulfonamides, afforded α-functionalized enoximes. Introduction of various nucleophiles proceeded smoothly to form C–N, C–O, C–S, C–F, and C–C bonds in the presence of azodicarboxylates.