Substituent effects on the solvolysis of 1, 1??diphenyl??2, 2, 2??trifluoroethyl tosylates. Part III. Effects of electron??donating substituents in the fixed aryl moiety

M Fujio, HJ Kim, H Morimoto, SD Yoh…

文献索引：Fujio, Mizue; Kim, Hyun-Joong; Morimoto, Hiroshi; Yoh, Soo-Dong; Tsuno, Yuho Journal of Physical Organic Chemistry, 1999 , vol. 12, # 11 p. 843 - 857

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被引用次数: 8

摘要

Abstract The solvolysis rates of 1-aryl-1-(p-methoxyphenyl)-2, 2, 2-trifluoroethyl and 1-aryl-1- (p-phenoxyphenyl)-2, 2, 2-trifluoroethyl bromides and chlorides were conductimetrically measured at 25.0 C in 80% aqueous ethanol. The solvolysis rates of 1-(p-methylphenyl)- fixed series were also set up to analyze the substituent effect. The substituent effects on these Y-series of solvolyses were analyzed on the basis of the Yukawa–Tsuno equation. ...