The Journal of Organic Chemistry

Photooxidations of sulfenic acid derivatives. 5. The reaction of singlet oxygen with ethyl phenyl sulfenate

EL Clennan, MF Chen

文献索引：Clennan, Edward L.; Chen, Ming-Fang Journal of Organic Chemistry, 1995 , vol. 60, # 20 p. 6444 - 6447

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被引用次数: 18

摘要

The relative rate constant of chemical removal of singlet oxygen from solution by 1 and adamantane adamantylidene, 3, was measured by the competitive kinetic method of Higgins, Foote, and Cheng.'O Since problems were encountered with 1 interacting with an intermediate formed in the reaction of 3 (vide infra) the oxidations of the these competing substrates were conducted side-by-side on a merry-go-round to ensure identical steady ...