Mercury-photosensitized reactions of 1, 4-dienes

J Meinwald, GW Smith

文献索引：Meinwald,J.; Smith,G.W. Journal of the American Chemical Society, 1967 , vol. 89, p. 4923 - 4932

全文：HTML全文

被引用次数: 18

摘要

Abstract: The gas-phase, mercury-photosensitized reactions of four 1, Cdienes (1, 9, 15, and 18) have been found to yield vinylcyclopropanes (2, 10, 17, and 20) as the major monomeric products. Accompanying these cyclization reactions, carbon skeleton rearrangements which yield isomeric 1, 4-dienes, cycloadditions to form bicyclo-[2.1. 0] pentanes, and partial reductions to give monoolefins were detected. All of these reactions were accom-panied ...