Tetrahedron

… : Reaction of areneselenenyl chlorides and 2-chloroalkyl phenyl selenides11Organoselenium Chemistry. 14. For part 13 see GH Schmid and DG Garrett, J. Org. Chem …

GH Schmid, DG Garratt

文献索引：Schmid, George H.; Garratt, Dennis G. Tetrahedron, 1985 , vol. 41, # 21 p. 4787 - 4792

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被引用次数: 3

摘要

The products of the title reaction depend upon the relative concentrations of reactants. With equimolar concentrations or an excess of 2-chloroalkyl phenyl selenide, the products are 1, 2-dicloroethane and a diaryldiselenide. When excess areneselenenyl chloride is used, the products are a diaryl diselenide and 2-chloroalkyl phenyl selenide dichloride. A mechanism involving nucleophilic displacement at selenenyl selenium is proposed to account for the ...