Journal of Organometallic Chemistry

Palladium complex-catalyzed germylation of allylic halides using (germyl) stannanes

T Nakano, K Ono, Y Senda, T Migita

文献索引：Nakano, Taichi; Ono, Kazuyoshi; Senda, Yoshiya; Migita, Toshihiko Journal of Organometallic Chemistry, 2001 , vol. 619, # 1-2 p. 313 - 317

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被引用次数: 0

摘要

(Triethylgermyl) tributylstannane reacts metal-selectively with allylic halides at room temperature (rt) in the presence of tris (dibenzylideneacetone) dipalladium, Pd2 (dba) 3CHCl3, to provide an alternative route to allylgermanes.(Dimethylphenylgermyl) tributylstannane regio-and stereoselectively reacts more readily with allylic halides than (triethylgermyl) tributylstannane affording the corresponding allylgermanes in quantitative ...