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Ring conformation and barrier to inversion of 1, 3-disilacyclobutane from low-frequency vibrational spectra

RM Irwin, JM Cooke, J Laane

文献索引:Irwin,R.M. et al. Journal of the American Chemical Society, 1977 , vol. 99, # 10 p. 3273 - 3278

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被引用次数: 56

摘要

Abstract: The far-infrared and low-frequency Raman spectra of 1, 3-disilacyclobutane and the far-infrared spectrum of 1, 3-disilacyclobutane-ll, 3, 3-d4 have been recorded and analyzed. The spectra consist of a large number of bands between 30 and 200 cm-'which correspond to transitions involving the excited states of the ring-inversion vibration. The potential energy function for this vibration was determined from the transition frequencies, ...