Oxidation of organic compounds with Cerium (IV). XX. Abnormally rapid rate of oxidative cleavage of (. beta.-trimethylsilylethyl) phenylmethanol

WS Trahanovsky, AL Himstedt

文献索引：Trahanovsky,W.S.; Himstedt,A.L. Journal of the American Chemical Society, 1974 , vol. 96, p. 7974 - 7976

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被引用次数: 18

摘要

Abstract: Tlie ceric ammonium nitrate (CAN) oxidation of (6-tert-butylethy1) phenylmethanol (1) at 80'in 50% aqueous acetonitrile gave a ratio of oxidative cleavage to ketone formation, determined by measuring the relative yield of benzaldehyde to@-/err-butylethyl phenyl ketone, of 3.27='c 0.07, and 44% of P-tert-butylethyl nitrate was produced. However, the CAN oxidation under identical conditions of (0-trimethylsilylethyl) phenylmethanol (2) ...