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Australian Journal of Chemistry

The chemistry of pyrrolic compounds. XLV. Haematoporphyrin derivative: haematoporphyrin diacetate as the main product of the reaction of haematoporphyrin with a …

PS Clezy, TT Hai, RW Henderson, LV Thuc

文献索引:Clezy, Peter S.; Hai, Ton That; Henderson, Robert W.; Thuc, Le van Australian Journal of Chemistry, 1980 , vol. 33, # 3 p. 585 - 597

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被引用次数: 45

摘要

Abstract A mixture of acetic and sulfuric acids converts haematoporphyrin into a complex mixture of porphyrins of which the main product has been characterized as the diacetate (1g). Other compounds identified in the reaction mixture were the known vinylporphyrins (1b- d),(1h) and (li) and the isomeric monoacetoxyethyl (monohydroxyethyl) porphyrins (11) and (1m). Analysis of the reaction mixture was complicated by the presence of 1'-ethoxyethyl ...