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The Nitration of 3, 4, 5, 6-Tetramethylbenzene-1, 2-Dicarbonitrile, 2, 3, 5, 6-Tetramethylbenzonitrile, 1, 2, 3-Trimethyl-4, 6-Dinitrobenzene and 1, 2, 4, 5-Tetramethyl-3, …

MP Hartshorn, JM Readman, WT Robinson…

文献索引:Hartshorn, Michael P.; Readman, Jennifer M.; Robinson, Ward T.; Sies, Christiaan W.; Wright Graeme J. Australian Journal of Chemistry, 1988 , vol. 41, # 3 p. 373 - 386

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被引用次数: 2

摘要

Abstract Nitration of 3, 4, 5, 6-tetramethylbenzene-1, 2-dicarbonitrile (1a) gives epimeric pairs of dinitro ketones (6a) and (7a), and hydroxy ketones (9) and (10), in addition to the benzyl nitrate (4) and phthalide (5). Nitration of 2, 3, 5, 6-tetramethylbenzonitrile (11) gives the epimeric dinitro ketones (15) and (16), in addition to the nitrobenzonitrile (12) and the nitrophthalide (13). Nitration of 1, 2, 3-trimethyl-4, 6-dinitrobenzene (17) gives ...