Mechanism of dichlorination of n-dodecane and chlorination of 1-chlorododecane adsorbed on ZSM-5 zeolite molecular sieves. A supramolecular structural …

…, N Han, X Lei, JR Fehlner, L Abrams

文献索引：Turro, Nicholas J.; Han, Nianhe; Lei, Xue-Gong; Fehlner, James R.; Abrams, Lloyd Journal of the American Chemical Society, 1995 , vol. 117, # 17 p. 4881 - 4893

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被引用次数: 13

摘要

Abstract: The product distributions produced by the photoinduced dichlorination of n- dodecane (nD) and the photoinduced monochlorination of 1-chlorododecane (1CD) adsorbed on two pentasil zeolites (silicalite and LZ-105) have been investigated. The results are explained in terms of a supramolecular model for which the mobile and diffusing chlorination reagents (CWC12) enter the zeolite particle from the external surface and ...