The generation of carbon monofluoride (CF) and an investigation of the products of its reaction with alkenes

M Rahman, ML McKee, PB Shevlin

文献索引：Rahman, M.; McKee, Michael L.; Shevlin, Philip B. Journal of the American Chemical Society, 1986 , vol. 108, # 20 p. 6296 - 6299

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被引用次数: 12

摘要

Abstract: The reaction of arc generated carbon atoms with CF4 at 77 K in the presence of alkene trapping agents results in the formation of fluorocyclopropanes and 1.1- difluoroalkanes. The fluorocyclopropanes are postulated to arise by addition of CF to the double bond generating a cyclopropyl radical which abstracts H. CF adds stereospecifically to olefins and gives both cis and trans fluorocyclopropanes with the trans generally ...